Binary and ternary deep eutectic solvent mixtures: Influence on methylene blue electropolymerisation

نویسندگان

چکیده

Binary and ternary deep eutectic solvent (DES) mixtures based on choline chloride, with ethylene glycol, oxalic acid, urea fructose, were used for the first time as media electropolymerisation of poly(methylene blue) (PMB) glassy carbon electrodes (GCEs) GCEs modified multiwalled nanotubes (MWCNTs). The influence different parameters such DES composition, presence MWCNTs and/or perchlorate dopant, polymer film properties was evaluated. films electrodeposited in characterized by cyclic voltammetry voltammetric characteristics observed depending conditions. This knowledge to determine best binary growth, a view electrochemical sensor applications. PMB-based electrode tested ascorbate sensing order demonstrate usefulness this platform.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Influence of Hierarchical Interfacial Assembly on Lipase Stability and Performance in Deep Eutectic Solvent.

Hierarchical systems that integrate nano- and macroscale structural elements can offer enhanced enzyme stability over traditional immobilization methods. Microparticles were synthesized using interfacial assembly of lipase B from Candida antarctica with (CLMP-N) and without (CLMP) nanoparticles around a cross-linked polymeric core, to characterize the influence of the hierarchical assembly on l...

متن کامل

Unraveling the cytotoxicity and metabolic pathways of binary natural deep eutectic solvent systems

In this study, the anticancer potential and cytotoxicity of natural deep eutectic solvents (NADESs) were assessed using HelaS3, PC3, A375, AGS, MCF-7, and WRL-68 hepatic cell lines. NADESs were prepared from choline chloride, fructose, or glucose and compared with an N,N-diethyl ethanolammonium chloride:triethylene glycol DES. The NADESs (98 ≤ EC50 ≥ 516 mM) were less toxic than the DES (34 ≤ E...

متن کامل

Solvatochromic Study on Binary Solvent Mixtures with Ionic Liquids

Solvent effects on 2,6-dichloro-4-(2,4,6-triphenyl-pyridinium-1-yl)phenolate [ET (33) dye] and 7diethylamino-3,4-benzophenoxazine-2-one (Nile Red) in binary mixtures of organic solvents (acetone, acetonitrile, propylene carbonate, methanol and ethane-1,2-diol) with 1,3-dialkyl imidazoliumbased ionic liquids were studied by UV-visible spectroscopy. Highly nonlinear behaviour of mixtures of alcoh...

متن کامل

Prussian blue nanospheres synthesized in deep eutectic solvents.

A novel route for controlled synthesis of Prussian blue nanospheres (PB NSs) with different sizes by using deep eutectic solvents (DES) as both solvent and template provider was demonstrated. The size-controlled PB NSs were obtained directly by the coordination of Fe(CN)(6)(4-) ion with Fe(3+) ion in the DES. The probable mechanism of formation of PB NSs was discussed based on the characterizat...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Electrochemistry Communications

سال: 2021

ISSN: ['1388-2481', '1873-1902']

DOI: https://doi.org/10.1016/j.elecom.2021.106967